Practice mode s- and p-Block Elements

Which Group IV tetrachloride is not hydrolysed by water at room temperature?

Correct answer B. CCl₄

Explanation

Carbon has no low-energy vacant d orbitals and is shielded by four large chlorine atoms, so water cannot attack it. SiCl₄ and the heavier tetrachlorides hydrolyse readily, releasing HCl.

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