Practice mode Carboxylic Acids

Why is thionyl chloride often preferred over PCl₅ for converting a carboxylic acid into an acyl chloride?

Correct answer C. The by-products SO₂ and HCl are gases and escape easily

Explanation

RCOOH + SOCl₂ → RCOCl + SO₂ + HCl. Both by-products are gases, so they leave the mixture and the acyl chloride is easily purified. PCl₅ leaves liquid POCl₃, which must be separated by distillation.

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